SECTION 1: CHEMICAL PRODUCT IDENTIFICATION
Trade Name : BOLERO CROMATICO INCI : Titanium Dioxide (And) Mica (And) Iron Oxide (C.I. 77491) Chemical Name: : Mica (and) Titanium Dioxide (and) Ferrous Oxide Material Uses : Pigment Chemical Family : Inorganic Pigment
SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients CAS # EINECS # EU Phrases
Mica 12001-26-2 310-127-6 S22/25/36Titanium Dioxide 13463-67-7 236-675-5
Iron Oxide 1309-37-1 215-168-2
SECTION 3: HAZARD IDENTIFICATION
Physical State and Appearance: Solid. (odorless, yellow-green pearlescent powder)
Emergency Overview: May cause respiratory tract, eye and skin irritation.
Routes of Entry: Eye contact. Inhalation. Ingestion (not anticipated).
Potential Acute Health Effects Eyes:May cause eye irritation. Symptoms include: itching and redness after contact. Skin: May cause mild skin irritation. Symptoms include: itching and redness after contact.
Inhalation: May cause respiratory tract irritation. Symptoms include: coughing, wheezing or shortness of breath when inhaled. Ingestion:Not an intended route of exposure. May be hazardous in case of ingestion. Symptoms include gastrointestinal tract upset and diarrhea.
Potential Chronic Health Effects
Additional information See Toxicological information (section 11) Medical Conditions Overexposure: Aggravated by Repeated or prolonged inhalation of any dust particulate may aggravate respiratory medical conditions.
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If symptoms persist, seek medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before reusing. Thoroughly clean shoes before reuse. If symptoms develop, seek medical attention.
Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms persist, seek medical attention.
Ingestion: Do not ingest. If this material is swallowed, call a physician immediately. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
SECTION 5: FIRE FIGHTING MEASURES
Flammability: Non-flammable Fire Fighting Media And Instructions: In case of fire, use water spray (fog), foam, dry chemical, or CO2 Protective Clothing (fire): Wear self-contained breathing apparatus and full protective clothing.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Small Spill and Leak Use a tool to scoop up solid or absorbed material and place into appropriate labeled waste container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional regulatory requirements.
Large Spill and Leak Use appropriate tools to put the spill material into a labeled waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional regulatory requirements. Check TLV in section 8 of MSDS and with local authorities.
Spill Kit information No specific spill kit required for this product.
SECTION 7: HANDLING AND STORAGE
Handling : Avoid generating dust. Avoid breathing dust. Use only with adequate ventilation. Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Keep container closed. Wash thoroughly after handling.
Storage : Keep container dry. Keep containers sealed until ready for use.
SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
| Exposure Levels: | OSHA | ACGIH | |
| Component TiO2 MicaIron Oxide | TWA 10 mg/m3 3 mg/m3 10 mg/m3 | PEL | TWA TLV 10 mg/m3 3 mg/m3 5 mg/m3 |
| Tin Oxide | 2 mg/m3 | 2 mg/m3 | |
| Personal Protection: |
Eye: Safety glasses with side shields or goggles Body: Lab coat Respiratory: Use NIOSH/MSHA approved air-purifying respirator as needed to control exposure. Hand: Recommended: Gloves
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
| Boiling Point (°C) | : | N/A | Percent Volatile By Vol. (%) | : | N/A |
| Freezing Point (°C) | : | N/A | Vapor Density (Air=1) | : | N/A |
| Melting Point (°C) | : | > 1000 | Evaporation Rate (Buac=1) | : | N/A |
| Vapor Pressure (mm hg) | : | N/A | Solubility In Water | : | Insoluble |
| Bulk Density (g/cbi.) | : | N/A | Appearance & Odor | : | yellow-green powder. No Odor |
| SECTION 10: STABILITY AND REACTIVITY | |||||
Stable: StableHazardous Polymerization: NoneIncompatibility: Strong oxidizing agents and srtong acids.Hazardous Decomposition Products: Nature of decomposition products is not known.
SECTION 11: TOXICOLOGICAL INFORMATION
Titanium Dioxide* Iron Oxide Skin Irritation : Dermal LD50 > 10 g/kg (Rabbit) No Data (Rabbit) Eye Irritation : No data Mild-Irritant
(rabbit) Average Draize score = 0.00 Acute Oral Toxicity : Non-toxic, LD50 > 25 g/kg (rat) Non-toxic, LD50 > 15 g/kg (rat) Inhalation LC50 : >6.82 mg/L (4 hour) LD50>5,000 g/kg *: Trochimowicz. et. Al., J. Appl. Tox. 8, 383-385 (1998)
| Mica | Tin Oxide | |
|---|---|---|
| Skin Irritation | No data | No data |
| Eye Irritation | No data | Not Irritant |
| Oral Toxicity (rat) | LD50 > 15,000 mg/kg | No data |
| Sensitization | Non-toxic | No data |
Chronic Effects on CARCINOGENIC EFFECTS: Classified None. By NIOSH [Titanium Dioxide]. Classified A4 (not
Humansclassifiable for human or animal.) by ACGIH, 3 (not classifiable for human.) by IARC [Titanium Dioxide]. Classified None. By NIOSH [Iron Oxide]. Classified A4 (not classifiable for human or animal.) by AGIH, 3 (not classifiable for human.) by IARC [Iron Oxide]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure to the substance at concentrations above exposure limits may cause respiratory damage. Target Organs: eyes, lungs, skin.
Acute Effects on Humans May cause skin, eye, and respiratory irritation.
Sensitization Repeated or prolonged exposure to the substance at concentrations above the exposure limits may cause respiratory tract and lung sensitization.
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity of the Products Of Biodegradation: N/A German Regulations:
Water pollutant class: nwg (own classification)
SECTION 13: DISPOSAL CONSIDERATIONS
EPA Waste Number Non-hazardous wasteTreatment Dispose of according to all federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
DOT Classification Not regulated. TDG Classification Not regulated. IMO/IMDG Classification Not regulated. ICAO/IATA Not regulated. Classification
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: No products were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada) Not controlled under WHMIS (Canada)
International Regulations
DSCL (EEC) S22/25/36- Do not breathe dust, avoid contact with eyes and wear suitable protective clothing.
International List
Australia (NICNAS): MICA; TITANIUM DIOXIDE; IRON OXIDE
JAPAN (MITI): MICA; TITANIUM DIOXIDE; IRON OXIDE Korea (TCCL): MICA; TITANIUM DIOXIDE; IRON OXIDE Philippines (RA6969): MICA; TITANIUM DIOXIDE; IRON OXIDE
State Regulations Pennsylvania RTK: TITANIUM DIOXIDE: (generic environmental hazard); IRON OXIDE: (generic environmental hazard) Massachusetts RTK: MICA; TITANIUM DIOXIDE; IRON OXIDE New Jersey: MICA; TITANIUM DIOXIDE; IRON OXIDE
SECTION 16: OTHER INFORMATION
Hazardous Material Information System [Ratings Key: 4= Highest hazard, 0= Lowest hazard] (U.S.A.)
| Health | 1 |
|---|---|
| Fire Hazard | 0 |
| Reactivity | 0 |
| Personal Protection | E |
EU S phrases : S22/25/36- Do not breathe dust, avoid contact with eyes and wear suitable protective clothing.
Date Prepared : June 29, 2004 By Eric Smith
Date Revised : September 28, 2004
